Temperature?Controlled Divergent Synthesis of Tetrasubstituted Alkenes and Pyrrolo[1,2? <i>a</i> ]indole Derivatives via Iridium Catalysis
نویسندگان
چکیده
We have achieved an Ir(III)-catalyzed temperature-controlled divergent synthesis of tetrasubstituted alkenes and pyrrolo[1,2-a]indole derivatives through C?H alkenylation/DG migration [3+2] annulation, respectively. This method has various advantageous features: a) excellent regio- stereoselectivity good functional group tolerance, b) broad substrate scope moderate to yields, c) mild redox-neutral reaction conditions operational simplicity.
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ژورنال
عنوان ژورنال: Asian Journal of Organic Chemistry
سال: 2021
ISSN: ['2193-5815', '2193-5807']
DOI: https://doi.org/10.1002/ajoc.202100476